Electrical properties of metallic deposits depend on their individual materials. The electric conduction usually consists of electrolytic conductivity and a capacitance component that is created by the polarizable particles- electrolyte interfaces. The components can be described using complex conductivity as the fundamental conception of the induced polarization (IP) method. Metallic minerals are, in fact, the semiconductors providing the substantial attention to the IP sensitivity on the semiconductors surface characteristics due to their strong IP response and their broad presence in geological, hydrocarbon, and environmental sites. In this study, IP behavior in semiconductors is studied as a new outline with aim to better understanding of IP mechanisms. With this in mind, the effect of electrochemical reactions on induced polarization response of semiconductors is also considered. Results showed that the especial electrical properties of semiconductors accompanying with petrophysical and measuring characteristics affect on the semiconductors induced polarization mechanism.